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c. Completed neutron radiation detection systems containing detectors meeting the conditions of paragraph a of this special provision must be transported as follows: (1) The detectors must be contained in a strong sealed outer casing; (2) The casing must contain include sufficient absorbent or adsorbent material to absorb or adsorb the entire gas contents; (3) The completed system must be packed in strong outer packagings capable of withstanding a 1.8 meter (5.9 feet) drop test without leakage unless a system's outer casing affords equivalent protection. N7 The hazard class or division number of the material must be marked on the package in accordance with 172.302 of this subchapter. 351 Ammonium chlorate, ammonium chlorate aqueous solutions, and mixtures of a chlorate with an ammonium salt are forbidden for transport. 172.101 Purpose and use of hazardous materials table - eCFR The capacity of each drum must not exceed 220 L (58 gallons). If the SADT of the technically pure substance is higher than 75 C, the technically pure substance and formulations derived from it are not self-reactive materials and, if not meeting any other hazard class, are not subject to the requirements of this subchapter. The table below gives the various types of Lead alloy solders. The chemical under pressure must be classed based on the hazard characteristics of the components in the propellant; the liquid; or the solid. PDF 4756 Federal Register /Vol. 88, No. 16/Wednesday, January 25, 2023 c. Each glass inner packaging is protected by a means of preventing puncture of the plastic bag (e.g., sleeves or cushioning) in the event of damage to the packaging (e.g., by crushing). The rechargeable lithium ion cells can only be charged from the primary lithium metal cells; ii. B61 Written procedures covering details of tank car appurtenances, dome fittings, safety devices, and marking, loading, handling, inspection, and testing practices must be approved by the Associate Administrator before any single unit tank car tank is offered for transportation. (1) Numeric provisions. Portable tank special provisions are designated with the abbreviation TP (tank provision) and are assigned to specific hazardous materials in Column (7) of the 172.101 Table. Ch 6.0b Flashcards | Quizlet Essentially, such SSolder complies with RoHS (Restriction of Hazardous Substances) regulations. b. The objects must be secured to the flat car, motor vehicle, intermodal container, or unitized by steel banding to wooden runners or pallets and the units secured to the flat car, motor vehicle, or freight container to prevent shifting, including relative motion between the objects, under conditions normally incident to transportation. N32 Aluminum materials of construction are not authorized for single packagings. Title 49 was last amended 2/03/2023. N78 Packages consisting of inner glass, earthenware, or polyethylene or other nonfragile plastic bottles or jars not over 0.5 kg (1.1 pounds) capacity each, or metal cans not over five pounds capacity each, packed in outer wooden boxes, barrels or kegs, or fiberboard boxes are authorized and need not conform to the requirements of part 178 of this subchapter. The standards for CTMVs capable of transporting multiple hazardous materials for blasting in bulk and non-bulk packagings (i.e., a multipurpose bulk truck (MBT)). j. Net weight of contents in fiberboard boxes may not exceed 29 kg (64 pounds). (3) B codes. Except when the liquids are fully absorbed in solid material contained in sealed bags, for single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. 33 Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited. The portable tank must not be used if the wall thickness is less than that prescribed by the applicable T code in Column (7) of the Table for this material. For this test, the provisions of paragraphs 16.6.1.2 except letter g, 16.6.1.3.1 to 16.6.1.3.6, 16.6.1.3.7(b) and 16.6.1.3.8 of the UN Manual of Tests and Criteria must be applied. The quantities of hazardous materials do not exceed those specified in 173.4a of this subchapter; and. This provision may be used for both domestic and international shipments. 131 This material may not be offered for transportation unless approved by the Associate Administrator. Specification 110A500W tanks must be stainless steel. Hazardous materials necessary for the safe and proper operation of the cargo transport unit (e.g., fire extinguishing systems and air conditioning systems), must be properly secured to or installed in the cargo transport unit and are not otherwise subject to this subchapter. B82 Cargo tanks and portable tanks are not authorized. B115 Rail cars, highway trailers, roll-on/roll-off bins, or other non-specification bulk packagings are authorized. A51 For aircraft batteries, irrespective of the quantity limitations specified in Column (9A) of the 172.101 Table or 175.75(c), wet cell batteries, UN2794 or UN2795, up to a limit of 100 kg net mass per package may be transported aboard passenger aircraft. With less than 10 percent formaldehyde, are not subject to this subchapter. Air must be eliminated from the vapor space by nitrogen or other means. Quantities of not more than 500 g per package with not less than 10 percent water by mass may also be classed in Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). This content is from the eCFR and may include recent changes applied to the CFR. Comparative fire testing between a package as prepared for transport (including the substance to be transported) and an identical package filled with water must show that the maximum temperature measured inside the packages during testing does not differ by more than 200 C (392 F). A hypochlorite solution, UN1791, is a Class 8 corrosive material. 135 Internal combustion engines installed in a vehicle must be described using Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. Lithium ion cells and batteries at a state of charge greater than 30 percent of their rated capacity may only be transported under conditions approved by the Associate Administrator in accordance with the requirements in 49 CFR part 107, subpart H. Guidance and methodology for determining the rated capacity can be found in sub-section 38.3.2.3 of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). If not impact resistant, the outer packaging should not be used as the sole means of protecting the battery terminals from damage or short circuiting. 440 When this material is transported by tank car, the offeror must ensure each tank car is remotely monitored for pressure and location. B90 Steel tanks conforming or equivalent to ASME specifications which contain solid or semisolid residual motor fuel antiknock mixture (including rust, scale, or other contaminants) may be shipped by rail freight or highway. A11 For combination packagings, when metal inner packagings are permitted, only specification cylinders constructed of metals which are compatible with the hazardous material may be used. (c) Tables of special provisions. (3) A flammable gas is a gas that meets the criteria in 173.115 of this subchapter. b. 65 The group of alkaline earth metals includes magnesium, calcium, strontium, and barium. TP40 The portable tank must not be transported when connected with spray application equipment. B3 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks and DOT 57 portable tanks are not authorized. A bulk packaging containing sulfur is not subject to the placarding requirements of subpart F of this part, if it is marked with the appropriate identification number as required by subpart D of this part. A56 Radioactive material with a subsidiary hazard of Division 4.2, Packing Group I, must be transported in Type B packages when offered for transportation by aircraft. 130 Batteries, dry, sealed, n.o.s., commonly referred to as dry batteries, are hermetically sealed and generally utilize metals (other than lead) and/or carbon as electrodes. If you have questions or comments regarding a published document please 391 Except for articles being transported by motor vehicle as a material of trade in accordance with 173.6 of this subchapter, articles containing hazardous materials of Division 2.3, or Division 4.2, or Division 4.3, or Division 5.1, or Division 5.2, or Division 6.1 (substances with an inhalation toxicity of Packing Group I) and articles containing more than one of the following hazards: (1) Gases of Class 2; (2) Liquid desensitized explosives of Class 3; or (3) Self-reactive substances and solid desensitized explosives of Division 4.1, may only be offered for transportation and transported under conditions approved by the Associate Administrator. 102 The ends of the detonating cord must be tied fast so that the explosive cannot escape. formatting. A7 Steel packagings must be corrosion-resistant or have protection against corrosion. TP16 The portable tank must be protected against over and under pressurization which may be experienced during transportation. c. The motor carrier must maintain a satisfactory safety rating as prescribed in 49 CFR part 385. This molecular arrangement is exactly the same as that for dithioketo QA [5]. Insulating materials must not promote corrosion to steel when wet. However, the design stress limits may not exceed 25 percent of the stress for 0 temper at the maximum design temperature of the cargo tank, as specified in the Aluminum Association's Aluminum Standards and Data (IBR, see 171.7 of this subchapter). Have accident damage protection which conforms with 178.345-8 of this subchapter; c. Have a MAWP or design pressure of at least 87 psig: and. B85 Cargo tanks must be marked with the name of the lading in accordance with the requirements of 172.302(b). This includes vehicles transported in a packaging. The toy plastic or paper caps must be in the form of sheets, strips, rolls, or individual caps; b. 172.101 Hazardous Materials Table (HMT). 1 CFR 1.1 will also bring you to search results. TP5 For a portable tank used for the transport of flammable refrigerated liquefied gases or refrigerated liquefied oxygen, the maximum rate at which the portable tank may be filled must not exceed the liquid flow capacity of the primary pressure relief system rated at a pressure not exceeding 120 percent of the portable tank's design pressure. Formulations with low nitrocellulose contents and neither showing dangerous properties when tested for their ability to detonate, deflagrate or explode when heated under defined confinement by the appropriate test methods and criteria in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter), nor classed as a Division 4.1 (flammable solid) when tested in accordance with the procedures specified in 173.124 of this subchapter (chips, if necessary, crushed and sieved to a particle size of less than 1.25 mm), are not subject to the requirements of this subchapter. N74 Packages consisting of tightly closed inner containers of glass, earthenware, metal or polyethylene, capacity not over 0.5 kg (1.1 pounds) securely cushioned and packed in outer wooden barrels or wooden or fiberboard boxes, not over 15 kg (33 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter. Openings for safety relief devices on multi-unit tank car tanks shall be plugged or blank flanged. See 173.306(h) of this subchapter. 64 The group of alkali metals includes lithium, sodium, potassium, rubidium, and caesium. A82 The quantity limits in columns (9A) and (9B) do not apply to human or animal body parts, whole organs or whole bodies known to contain or suspected of containing an infectious substance. 335 Mixtures of solids that are not subject to this subchapter and environmentally hazardous liquids or solids may be classified as Environmentally hazardous substances, solid, n.o.s, UN3077 and may be transported under this entry, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. 325 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN 2978. 38 If this material shows a violent effect in laboratory tests involving heating under confinement, the labeling requirements of Special Provision 53 apply, and the material must be packaged in accordance with packing method OP6 in 173.225 of this subchapter. 352 Ammonium chlorite, ammonium chlorite aqueous solutions, and mixtures of a chlorite with an ammonium salt are forbidden for transport. Each tank car must have a reclosing pressure relief device having a start-to-discharge pressure of 10.34 Bar (150 psig). 371 a. 132 This description may only be used for ammonium nitrate-based compound fertilizers. If a tank car tank is equipped with a reclosing pressure relief valve, the tank must also be equipped with a vacuum relief valve. 171 This entry may only be used when the material is transported in non-friable tablet form or for granular or powered mixtures that have been shown to meet the PG III criteria in 173.127. Except for transportation by aircraft, in palletized loads, a pallet box or unit load device (e.g. Explosives shipped in conformance with this paragraph must have been examined in accordance with 173.56 of this subchapter and approved by the Associate Administrator. B120 The use of flexible bulk containers conforming to the requirements in subpart R and subpart S of part 178 of this subchapter is permitted. They must be classified in accordance with the procedure as set out in the Manual of Tests and Criteria, part III, section 39 (IBR, see 171.7 of this subchapter). information or personal data. These special provisions are in addition to the standard packaging requirements. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. (TOY CAPS) - HANDLE CAREFULLY OR TOY CAPS - HANDLE CAREFULLY; and. B27 Tanks must have a service pressure of 1,034 kPa (150 psig). TP29 A portable tank having a minimum test pressure of 1.5 bar (150.0 kPa) may be used provided the calculated test pressure is 1.5 bar or less based on the MAWP of the hazardous materials, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. The purpose of this article is to explain the meaning of the coding system for the Special Provisions of column 7 in order to facilitate your review and understanding of them and how they may apply to your shipment of a hazardous material. 43 The membrane filters, including paper separators and coating or backing materials, that are present in transport, must not be able to propagate a detonation as tested by one of the tests described in the UN Manual of Tests and Criteria, Part I, Test series 1(a) (IBR, see 171.7 of this subchapter). TP31 This hazardous material may only be transported in tanks in the solid state. The batteries must be securely attached to the interior structure of the cargo transport unit (e.g., by means of placement in racks, cabinets, etc.) They must be classified in accordance with the procedure as set out in the Manual of Tests and Criteria, part III, section 39 (IBR, see 171.7 of this subchapter). a. Mixtures of one or more organic lead mixtures (such as tetraethyl lead, triethylmethyl lead, diethyldimethyl lead, ethyltrimethyl lead, and tetramethyl lead) with one or more halogen compounds (such as ethylene dibromide and ethylene dichloride), hydrocarbon solvents or other equally efficient stabilizers; or. UN2258, 1,2-Propylenediamine: In HM-260B, PHMSA removed special provision A6 from column (7) of the . (iii) Constructing the battery with terminals that are recessed or otherwise protected so that the terminals will not be subjected to damage if the package is dropped. Flammable components are flammable liquids and liquid mixtures, flammable solids and solid mixtures or flammable gases and gas mixtures meeting the following criteria: (1) A flammable liquid is a liquid having a flashpoint of not more than 93 C (200 F); (2) A flammable solid is a solid that meets the criteria in 173.124 of this subchapter; or. These substances must satisfy the criteria for classification as an ammonium nitrate emulsion of Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18 (IBR, see 171.7 of this subchapter), and may not be classified and transported unless approved by the Associate Administrator. Where different hazardous materials in limited quantities are packed together in the same outer packaging, when a gross mass is indicated Column 4 of 173.27 Table 3, the net quantity of each hazardous material must be shown in addition to the gross mass of the completed package. The presence of a Class 8 hazard must be communicated as required by this part for subsidiary hazards. PDF Special Provision Letter Codes Used in Hazmat Table, Column 7 f. Flexible: 13H2, 13H3, 13H4, 13H5, 13L2, 13L3, 13L4, 13M1 and 13M2 (flexible IBCs must be sift-proof and water resistant or must be fitted with a sift-proof and water resistant liner). 23 This material may be transported under the provisions of Division 4.1 only if it is so packed that the percentage of diluent will not fall below that stated in the shipping description at any time during transport. Batteries contained in devices must be securely installed. TP8 A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 C (32 F). Alternatively, the item itself may be used as a packaging if it meets the general packaging requirements of subparts A and B of part 173 of this subchapter. 41 This material at the Packing Group II hazard criteria level may be transported in Large Packagings. 388 a. Lithium batteries containing both primary lithium metal cells and rechargeable lithium ion cells that are not designed to be externally charged, must meet the following conditions: i. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. Wooden boxes must be completely lined with a suitable material impervious to water and nitroglycerin. 49 CFR 172.101 B57 Class 115A tank car tanks used to transport chloroprene must be equipped with a non-reclosing pressure relief device of a diameter not less than 305 mm (12 inches) with a maximum rupture disc pressure of 310 kPa (45 psig). In addition to the provisions applicable to the transport of Division 6.1 substances, the provisions of 173.421(c) and 173.443(a) of this subchapter apply. B59 Water-tight, sift-proof, closed-top, metal-covered hopper cars are also authorized provided that the lading is covered with a nitrogen blanket. 167 These storage systems must always be considered as containing hydrogen. B5 Only ammonium nitrate solutions with 35 percent or less water that will remain completely in solution under all conditions of transport at a maximum lading temperature of 116 C (240 F) are authorized for transport in the following bulk packagings: MC 307, MC 312, DOT 407 and DOT 412 cargo tanks with at least 172 kPa (25 psig) design pressure. Different Types of Solder- All Common Classifications Compressed air containing greater than 23.5 percent oxygen must be shipped using the description Compressed gas, oxidizing, n.o.s., UN3156.. PDF 173.242 49 CFR Ch. I (10-1-04 Edition) - GovInfo Use of these proper shipping names for domestic shipments may be made only under a DOT special permit, as defined in, and in accordance with the requirements of subpart B of part 107 of this subchapter. These entries include hybrid electric vehicles powered by both an internal combustion engine and batteries. Net weight of contents in wooden boxes, barrels or kegs may not exceed 45 kg (99 pounds). The cargo transport unit shall display the UN number in a manner in accordance with 172.332 of this subchapter and be placarded on two opposing sides. 59 Ferrocerium, stabilized against corrosion, with a minimum iron content of 10 percent is not subject to the requirements of this subchapter. 159 This material must be protected from direct sunshine and kept in a cool, well-ventilated place away from sources of heat. 8 A hazardous substance that is not a hazardous waste may be shipped under the shipping description Other regulated substances, liquid or solid, n.o.s., as appropriate. c. Self-propelled vehicles or equipment that also contain an internal combustion engine must be described using the entries Engine, internal combustion, flammable gas powered or Engine, internal combustion, flammable liquid powered or Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. For other than Class 7 or the DANGEROUS . c. Where the liquid or solid components are classed as Division 6.1, Packing Group II or III, or Class 8, Packing Group II or III, the chemical under pressure must be assigned a subsidiary risk of Division 6.1 or Class 8 and the appropriate identification number must be assigned. As a (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the subpart E (labeling) requirements of this part when offered for transportation by motor vehicle, rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned in 173.62 of this subchapter, in conformance with the following conditions: a. An important, but often overlooked, requirement for the safe and regulatory compliant transportation of a HazMat is an understanding of the special provisions in column 7 of the Hazardous Materials Table. Cargo and portable tanks must have a design pressure of at least 1,207 kPa (175 psig). N8 Nitroglycerin solution in alcohol may be transported under this entry only when the solution is packed in metal cans of not more than 1 L capacity each, overpacked in a wooden box containing not more than 5 L. Metal cans must be completely surrounded with absorbent cushioning material. Single unit tank car tanks must have a reclosing pressure relief device having a start-to-discharge pressure set at no more than 1551 kPa (225 psig). B80 Each cargo tank must have a minimum design pressure of 276 kPa (40 psig). The requirements of 173.24(g)(1) and 173.27(c) do not apply. N83 This material may not be transported in quantities of more than 11.5 kg (25.4 lbs) per package. 338 Life Saving appliances, self-inflating transported by motor vehicle only between an U.S. Coast Guard approved inflatable life raft servicing facility and a vessel are only subject to the following requirements: a. (h) Column 7: Special provisions. (5) Each receptacle shall be able to withstand a pressure of 20 bar (2000 kPa) without leakage when the pressure relief device is deactivated. Test of type 3(c) is not required. B30 MC 312, MC 330, MC 331 and DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. 157 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.151(b)(1)(i) of this subchapter for inner packagings may be increased to 5 kg (11 pounds). Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. authorized by name in the Hazardous Materials Table or have been specifically authorized by name either in the Section 172.101 Hazardous Materials Table or have been assigned a shipping name and hazard class by the Associate Administrator for Hazardous Materials Safety. b. 19 For domestic transportation only, the identification number UN1075 may be used in place of the identification number specified in column (4) of the 172.101 table. Your Nuclear Attack Map for 2023 - mirasafety.com Symbol Meaning Which is the correct column for hazardous materials? a. 347 Effective July 1, 2011, for transportation by aircraft, this entry may only be used if the results of Test series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. Prior to repacking into the life-saving appliance, an installed inflation cylinder must successfully meet and pass all inspection and test criteria and standards of the raft manufacturer and the vessel Flag State requirements for cylinders installed as part of life-saving appliances, self-inflating (UN2990) used on marine vessels. The requirements of 172.203(m) and 172.505 of this subchapter do not apply. Such articles must comply with the following requirements: (1) The water capacity of the pressure receptacle must not exceed 0.5 L and the working pressure must not exceed 25 bar at 15 C (59 F); (2) The minimum burst pressure of the pressure receptacle must be at least four times the pressure of the gas at 15 C (59 F); (3) Each article must be manufactured in such a way that unintentional firing or release is avoided under normal conditions of handling, packing, transport and use. B134 For Large Packagings offered for transport by vessel, flexible or fibre inner packagings shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. How to Read the Hazardous Materials Table If they do leak, they must be overpacked in packagings conforming to the specification requirements of part 178 of this subchapter or in salvage packagings conforming to the requirements in 173.12 of this subchapter. d. Receptacles containing adsorbed or absorbed ammonia shall meet the following conditions: (1) Receptacles shall be made of a material compatible with ammonia as specified in ISO 11114-1:2012(E) and ISO 11114-1:2012/Amd 1:2017(E) (IBR, see 171.7 of this subchapter); (2) Receptacles and their means of closure shall be hermetically sealed and able to contain the generated ammonia; (3) Each receptacle shall be able to withstand the pressure generated at 85 C (185 F) with a volumetric expansion no greater than 0.1%; (4) Each receptacle shall be fitted with a device that allows for gas evacuation once pressure exceeds 15 bar (1500 kPa) without violent rupture, explosion or projection; and. We recommend you directly contact the agency responsible for the content in question. 170 Air must be eliminated from the vapor space by nitrogen or other means. (3) When no bottom openings are authorized, the alternative portable tank must not have bottom openings. Non-specification bulk bins are authorized. 11 The hazardous material must be packaged as either a liquid or a solid, as appropriate, depending on its physical form at 55 C (131 F) at atmospheric pressure. Other inorganic nitrate salts may replace part of the ammonium nitrate. The Associate Administrator may except from the requirements of this subchapter articles, machinery, and apparatus provided: a. A29 Combination packagings consisting of outer expanded plastic boxes with inner plastic bags are not authorized for transportation by aircraft. Each IBC may not exceed a maximum net quantity of 1,000 kg: a. Column 5 references applicable requirements for bottom openings in part 178 of this subchapter. Heater pipes must be of welded construction designed for a test pressure of 500 psig. These provisions apply only to transportation by water: W1 This substance in a non friable prill or granule form is not subject to the requirements of this subchapter when tested in accordance with the UN Manual of Test and Criteria (IBR, see 171.7 of this subchapter) and is found to not meet the definition or criteria for inclusion in Division 5.1. A53 Refrigerating machines and refrigerating machine components are not subject to the requirements of this subchapter when containing less than 12 kg (26.4 pounds) of a non-flammable gas or when containing 12 L (3 gallons) or less of ammonia solution (UN2672) (see 173.307 of this subchapter). These batteries are typically used for portable power applications. These special provisions are in addition to the standard packaging requirements. B55 Water-tight, sift-proof, closed-top, metal-covered hopper cars, equipped with a venting arrangement (including flame arrestors) approved by the Associate Administrator are also authorized. Radiation detectors transported as individual components must be transported as follows: (1) They must be packed in a sealed intermediate plastic liner with sufficient absorbent or adsorbent material to absorb or adsorb the entire gas contents. d. All inner packagings placed inside bulk outer packagings must be blocked and braced to prevent shifting during transportation that could cause the container to open or fall over. When column 7 of the 172.101 table refers to a special provision for a hazardous material, the meaning and requirements of that provision are as set forth in this section.